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CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
***Click the ANX, Pearson or Wyckoff Symbol to find structures with that symbol***.
CC=51156 Help
TitleStructural, infrared, and magnetic characterization of the solid solution series Sr(2-x) Pb(x) (V O)(V O4)2; evidence of the Pb(2+) 6s2 lone pair stereochemical effect.
AuthorsMentre, O.;Dhaussy, A.-C.;Abraham, F.;Steinfink, H.
ReferenceJournal of Solid State Chemistry (1998) 140, 417-427
Link XRef SCOPUS SCIRUS Google
CompoundO9 Pb1.33 Sr0.67 V3 - Strontium lead oxovanadium(IV) vanadate (0.67/1.33/1/2) [A2B3X9] [mS56] [f9 e3] []
Cell7.588(1), 16.350(20), 6.958(8), 90., 119.64(5), 90.
C12/C1 (15) V=750.28
RemarksR=0.060000 : DEF
The coordinates are those given in the paper but the atomic distances do not agree with those calculated during testing.The coordinates are probably correct.

Atom (site) Oxid. x, y, z, B, Occupancy
Sr1(8f)2
Pb1(8f)2
Sr2(8f)2
Pb2(8f)2
V1(4e)4.667
V2(8f)4.667
V3(4e)4.667
V4(8f)4.667
V5(8f)4.667
O1(8f)-2
O2(8f)-2
O3(8f)-2
O4(8f)-2
O5(4e)-2
0.0079(39)-.1249(1)0.2361(41)00.18(1)
0.0079(39)-.1249(1)0.2361(41)00.32
-.0247(18)0.4525(1)0.2369(39)00.155(1)
-.0247(18)0.4525(1)0.2369(39)00.345
00.6589(8)0.2500.7
0.0361(29)0.6633(22)0.289(3)0.40.15
00.0793(11)0.2500.7
0.0290(36)0.0826(27)0.2844(35)0.40.15
0.2961(8)0.7558(4)0.0478(10)00.5
0.1637(19)0.7225(7)0.2187(21)1.93(45)1
0.1632(20)0.0207(7)0.2212(24)2.46(51)1
0.3888(20)0.0971(7)0.0248(21)1.90(45)1
0.8552(18)0.1397(6)0.0092(21)1.32(38)1
00.2837(6)0.251.65(33)1
Atom (site) Oxid. Beta11, Beta22, Beta33, Beta12, Beta13, Beta23
Sr1(8f)2
Pb1(8f)2
Sr2(8f)2
Pb2(8f)2
V1(4e)4.667
V2(8f)4.667
V3(4e)4.667
V4(8f)4.667
V5(8f)4.667
O1(8f)-2
O2(8f)-2
O3(8f)-2
O4(8f)-2
O5(4e)-2
0.013(1)0.00116(6)0.022(2)0.0003(2)0.0174(8)0.00015(28)
0.013(1)0.00116(6)0.022(2)0.0003(2)0.0174(8)0.00015(28)
0.009(2)0.00133(6)0.0712(2)0.0001(2)0.011(2)-.00001(29)
0.009(2)0.00133(6)0.0712(2)0.0001(2)0.011(2)-.00001(29)
0.002(1)0.0005(1)0.0027(9)00.002(5)0
000000
0.0005(11)0.0007(2)0.006(1)00.008(4)0
000000
0.002(2)0.0003(2)0.007(2)0.0002(5)0.004(1)0.00002(64)
000000
000000
000000
000000
000000

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