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1 entry selected.
CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
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CC=35687 Help
Title... The Use of Sulfido Ligands in the Synthesis of High Nuclearity Transition-Metal Cluster Compounds. The Synthesis and Crystal and Molecular Structures of Os6 (C O)17 (mue4-S)2 and Os6 (C O)16 (mue4-S) (mue3-S).
AuthorsAdams, R.D.;Horvath, I.T.;Yang, L.W.
ReferenceIC&volume=105&fpage=153&details=yes target=icsd_help>Journal of the American Chemical Society (1983) 105, 153-153
Link XRef SCOPUS Google
CompoundC17 O17 Os6 S2 - 17-carbonyl-di-!-mue4-thio-hexaosmium [A17N2O6X17] [oP168] [a42] []
Cell11.280(5), 14.622(8), 17.626(5), 90., 90., 90.
P212121 (19) V=2907.16
RemarksR=0.037000 :
The coordinates are those given in the paper but the atomic distances do not agree with those calculated during testing.The coordinates are probably correct.

Atom (site) Oxid. x, y, z, B, Occupancy
Os1(4a)0
Os2(4a)0
Os3(4a)0
Os4(4a)0
Os5(4a)0
Os6(4a)0
S1(4a)0
S2(4a)0
O1(4a)-2
O2(4a)-2
O3(4a)-2
O4(4a)-2
O5(4a)-2
O6(4a)-2
O7(4a)-2
O8(4a)-2
O9(4a)-2
O10(4a)-2
O11(4a)-2
O12(4a)-2
O13(4a)-2
O14(4a)-2
O15(4a)-2
O16(4a)-2
O17(4a)-2
C1(4a)2
C2(4a)2
C3(4a)2
C4(4a)2
C5(4a)2
C6(4a)2
C7(4a)2
C8(4a)2
C9(4a)2
C10(4a)2
C11(4a)2
C12(4a)2
C13(4a)2
C14(4a)2
C15(4a)2
C16(4a)2
C17(4a)2
-.72-.43-.1901
-.74-.59-.0901
-.54-.56-.1801
-.87-.30-.1001
-.97-.40-.2201
-.96-.49-.0701
-.88-.54-.192.51
-.75-.43-.052.51
-.69-.43-.366.11
-.52-.29-.184.31
-.76-.78-.136.1
-.59-.630.045.21
-.38-.72-.154.61
-.37-.47-.296.31
-.45-.45-.044.41
-.67-.66-.324.61
-.79-.210.039.1
-1.0-.19-.106.61
-.75-.15-.195.61
-.93-.23-.326.51
-1.2-.35-.196.31
-1.0-.51-.376.61
-1.0-.390.067.21
-.96-.660.014.71
-1.2-.55-.105.81
-.70-.43-.302.81
-.60-.34-.192.91
-.75-.71-.114.41
-.65-.62-.013.41
-.44-.66-.162.51
-.43-.50-.245.1
-.48-.50-.094.11
-.62-.63-.262.61
-.83-.24-.017.71
-1.0-.23-.103.81
-.80-.21-.154.31
-.94-.29-.283.81
-1.1-.37-.214.91
-1.0-.47-.324.61
-1.0-.420.014.71
-.93-.61-.032.11
-1.1-.52-.093.31
Atom (site) Oxid. B11, B22, B33, B12, B13, B23
Os1(4a)0
Os2(4a)0
Os3(4a)0
Os4(4a)0
Os5(4a)0
Os6(4a)0
S1(4a)0
S2(4a)0
O1(4a)-2
O2(4a)-2
O3(4a)-2
O4(4a)-2
O5(4a)-2
O6(4a)-2
O7(4a)-2
O8(4a)-2
O9(4a)-2
O10(4a)-2
O11(4a)-2
O12(4a)-2
O13(4a)-2
O14(4a)-2
O15(4a)-2
O16(4a)-2
O17(4a)-2
C1(4a)2
C2(4a)2
C3(4a)2
C4(4a)2
C5(4a)2
C6(4a)2
C7(4a)2
C8(4a)2
C9(4a)2
C10(4a)2
C11(4a)2
C12(4a)2
C13(4a)2
C14(4a)2
C15(4a)2
C16(4a)2
C17(4a)2
2.202.211.990.010.08-.04
2.932.282.100.04-.05-.01
2.172.692.55-.13-.060.19
2.662.302.520.100.02-.26
2.482.782.140.14-.16-.01
2.483.091.980.130.120.05
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