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1 entry selected.
CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
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CC=49690 Help
TitleStructural Characterization and Infrared Studies of Tungsten Bromo Carbonyl Compounds.
AuthorsCotton, F.A.;Falvello, L.R.;Meadows, J.H.
ReferenceInorganic Chemistry (1985) 24, 514-517
Link XRef SCOPUS Google
CompoundC7 Br4 O7 W2 - Tetrabromoheptacarbonylditungsten [A7N2O4X7] [oP80] [d5 c10] []
Cell20.249(4), 8.058(2), 9.670(2), 90., 90., 90.
PNMA (62) V=1577.82
RemarksR=0.036000 :
The coordinates are those given in the paper but the atomic distances do not agree with those calculated during testing.The coordinates are probably correct.

Atom (site) Oxid. x, y, z, B, Occupancy
W1(4c)0
W2(4c)0
Br1(4c)0
Br2(8d)0
Br3(4c)0
O1(4c)-2
O2(8d)-2
O3(4c)-2
O4(4c)-2
O5(8d)-2
C1(4c)2
C2(8d)2
C3(4c)2
C4(4c)2
C5(8d)2
0.400.250.142.201
0.350.25-.212.151
0.300.250.313.871
0.330.46-.013.781
0.470.25-.083.801
0.450.25-.454.5(1
0.330.57-.394.8(1
0.200.25-.284.6(1
0.550.250.236.0(1
0.420.550.335.2(1
0.410.25-.372.2(1
0.340.46-.323.7(1
0.250.25-.262.9(1
0.490.250.204.7(1
0.410.440.273.6(1

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