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CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
***Click the ANX, Pearson or Wyckoff Symbol to find structures with that symbol***.
CC=60075 Help
TitleCo-ordination chemistry of higher oxidation states. Part 13. Synthesis and properties of alkali-metal hydroxo-oxo-osmate(VIII) compounds and the molecular structure of Cs (O4 Os (mue-O H) Os O4)..
AuthorsJewiss, H.C.;Leavason, W.;Tajik, M.;Webster, M.;Walker, N.P.C.
ReferenceIC&volume=1985&fpage=199&details=yes target=icsd_help>Journal of the Chemical Society. Dalton (1985) 1985, 199-203
Link XRef SCOPUS Google
CompoundH1 Cs1 O9 Os2 - Caesium !-mue-oxo-bis(tetraoxoosmate(VIII)) [AB2X9] [mS52] [a12] []
Cell14.304(4), 5.798(1), 10.527(4), 90., 109.92(3), 90.
C1C1 (9) V=820.82
RemarksR=0.059000 :

Atom (site) Oxid. x, y, z, B, Occupancy
Os1(4a)8
Os2(4a)8
Cs1(4a)1
O1(4a)-2
O2(4a)-2
O3(4a)-2
O4(4a)-2
O5(4a)-2
O6(4a)-2
O7(4a)-2
O8(4a)-2
O9(4a)-2
H1(4a)1
00.02001
0.170.440.8701
-.150.500.7301
0.10-.000.120.021
-.000.000.840.031
-.070.220.020.021
-.06-.210.010.031
0.070.350.970.011.
0.260.510.790.041
0.210.160.920.031
0.070.470.740.011
0.210.630.980.041
01.
Atom (site) Oxid. U11, U22, U33, U12, U13, U23
Os1(4a)8
Os2(4a)8
Cs1(4a)1
O1(4a)-2
O2(4a)-2
O3(4a)-2
O4(4a)-2
O5(4a)-2
O6(4a)-2
O7(4a)-2
O8(4a)-2
O9(4a)-2
H1(4a)1
0.010.010.010.000.010.00
0.010.010.010.000.00-.00
0.020.020.030.000.010.00
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000

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