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CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
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Title
Kristallstruktur-Verfeinerungen an Rubidiumtetrafluorometallaten(II): Rb2 M F4 (M=Mg, Co, Ni).
Authors
Welsch, M.;Babel, D.
Reference
Zeitschrift fuer Naturforschung, Teil B. (1991)
46
, 161-164
Link
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Also:
Zeitschrift fuer Anorganische und Allgem (1962)
317
, 261-287
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Also:
Naturwissenschaften (1962)
49
, 230-230
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Compound
F4 Ni1 Rb2
- Dirubidium tetrafluoroniccolate
[
AB2X4
] [
tI14
] [
e2 c a
] [
K2MgF4
]
Cell
4.086(1), 4.086(1), 13.708(3), 90., 90., 90.
I4/MMM (139)
V=228.86
Remarks
R=0.032000 : T =K2MgF4 :
(N H4)2 Ni F4: 4.08, 13.7, Dm=2.39; Rb2 Cu F4: 4.23, 13.2
Tl2 Ni F4: 4.05, 14.2, Dm=7.85; Tl2 Cu F4: 4.19, 13.6
Cells of isotypic compounds (2nd and 3rd reference):
Atom (site) Oxid.
x, y, z, B, Occupancy
Rb1
(4e)
1
Ni1
(2a)
2
F1
(4e)
-1
F2
(4c)
-1
0
0
0.35
0
1
0
0
0
0
1
0
0
0.14
0
1
0.5
0
0
0
1
Atom (site) Oxid.
U11, U22, U33, U12, U13, U23
Rb1
(4e)
1
Ni1
(2a)
2
F1
(4e)
-1
F2
(4c)
-1
0.01
0.01
0.01
0
0
0
0.00
0.00
0.01
0
0
0
0.01
0.01
0.01
0
0
0
0.00
0.01
0.01
0
0
0
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