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CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
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CC=87621 Help
TitleThe crystal structures at 10 K of the trigonal salts K M(III) (N H3)6 (Cl O4)2 Cl2, M(III)=Os and Cr, and the possibility of phase transitions.
AuthorsReynolds, P.A.;Figgis, B.N.;Sobolev, A.N.
ReferenceIC&volume=52&fpage=219&details=yes target=icsd_help>Australian Journal of Chemistry (1999) 52, 219-225
Link XRef SCOPUS Google
CompoundH18 Cl4 Cr1 K1 N6 O8 - Potassium hexaamminechromium(III) bis(chlorate(VII)) dichloride [ABC2X2Y6Z8] [hR38] [f2 c3 b a] []
Cell6.9575(3), 6.9575(3), 27.2050(20), 90., 90., 120.
R3-H (148) V=1140.48
RemarksR=0.025000 : T =11 : M =Cl :
The coordinates are those given in the paper but the atomic distances do not agree with those calculated during testing.The coordinates are probably correct.

Atom (site) Oxid. x, y, z, B, Occupancy
Cr1(3a)3
N1(18f)-3
Cl1(6c)7
O1(6c)-2
O2(18f)-2
Cl2(6c)-1
K1(3b)1
H1(18f)1
H2(18f)1
H3(18f)1
00001
0.130.840.8501.
000.1801
000.1301
0.120.890.2001
000.3801
000.501
0.220.81-.020.021
0.21-.07-.060.021
0.040.72-.050.041
Atom (site) Oxid. U11, U22, U33, U12, U13, U23
Cr1(3a)3
N1(18f)-3
Cl1(6c)7
O1(6c)-2
O2(18f)-2
Cl2(6c)-1
K1(3b)1
H1(18f)1
H2(18f)1
H3(18f)1
0.000.000.000.0000
0.000.000.000.000.000.00
0.000.000.000.0000
0.010.010.000.0000
0.000.000.000.00-.000.00
0.000.000.000.0000
0.000.000.000.0000
000000
000000
000000

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