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1 entry selected.
CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
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CC=51156 Help
TitleStructural, infrared, and magnetic characterization of the solid solution series Sr(2-x) Pb(x) (V O)(V O4)2; evidence of the Pb(2+) 6s2 lone pair stereochemical effect.
AuthorsMentre, O.;Dhaussy, A.-C.;Abraham, F.;Steinfink, H.
ReferenceIC&volume=140&fpage=417&details=yes target=icsd_help>Journal of Solid State Chemistry (1998) 140, 417-427
Link XRef SCOPUS Google
CompoundO9 Pb1.33 Sr0.67 V3 - Strontium lead oxovanadium(IV) vanadate (0.67/1.33/1/2) [A2B3X9] [mS56] [f9 e3] []
Cell7.588(1), 16.350(20), 6.958(8), 90., 119.64(5), 90.
C12/C1 (15) V=750.28
RemarksR=0.060000 : D
The coordinates are those given in the paper but the atomic distances do not agree with those calculated during testing.The coordinates are probably correct.

Atom (site) Oxid. x, y, z, B, Occupancy
Sr1(8f)2
Pb1(8f)2
Sr2(8f)2
Pb2(8f)2
V1(4e)4.667
V2(8f)4.667
V3(4e)4.667
V4(8f)4.667
V5(8f)4.667
O1(8f)-2
O2(8f)-2
O3(8f)-2
O4(8f)-2
O5(4e)-2
0.00-.120.2300.18
0.00-.120.2300.32
-.020.450.2300.15
-.020.450.2300.34
00.650.2500.7
0.030.660.280.40.15
00.070.2500.7
0.020.080.280.40.15
0.290.750.0400.5
0.160.720.211.931
0.160.020.222.461
0.380.090.021.901
0.850.130.001.321
00.280.251.651
Atom (site) Oxid. Beta11, Beta22, Beta33, Beta12, Beta13, Beta23
Sr1(8f)2
Pb1(8f)2
Sr2(8f)2
Pb2(8f)2
V1(4e)4.667
V2(8f)4.667
V3(4e)4.667
V4(8f)4.667
V5(8f)4.667
O1(8f)-2
O2(8f)-2
O3(8f)-2
O4(8f)-2
O5(4e)-2
0.010.000.020.000.010.00
0.010.000.020.000.010.00
0.000.000.070.000.01-.00
0.000.000.070.000.01-.00
0.000.000.0000.000
000000
0.000.000.0000.000
000000
0.000.000.000.000.000.00
000000
000000
000000
000000
000000

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