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CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
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Title
Crystal chemistry of the new mineral brandholzite, Mg (H2 O)6 (Sb (O H)6)2, and of the synthetic analogues M(2+) (H2 O)6 (Sb (O H)6)2(M(2+) = Mg, Co).
Authors
Friedrich, A.;Wildner, M.;Tillmanns, E.;Merz, P.L.
Reference
IC&volume=85&fpage=593&details=yes target=icsd_help>American Mineralogist (2000)
85
, 593-599
Link
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Compound
H24 Co1 O18 Sb2
-
[Unnamed]
Hexaaquacobalt bis(hexahydroxoantimonate)
[
AB2X18
] [
hP270
] [
d40 c2 b2 a2
] [
]
Cell
16.105(1), 16.105(1), 9.851(1), 90., 90., 120.
P3 (143)
V=2212.75
Remarks
R=0.051000 : T M =Unnamed :
Atom (site) Oxid.
x, y, z, B, Occupancy
Sb1
(1a)
5
Sb2
(1c)
5
Sb3
(1b)
5
Co1
(3d)
2
Co2
(3d)
2
O1
(3d)
-2
O2
(3d)
-2
O3
(3d)
-2
O4
(3d)
-2
O5
(3d)
-2
O6
(3d)
-2
O7
(3d)
-2
O8
(3d)
-2
O9
(3d)
-2
O10
(3d)
-2
O11
(3d)
-2
O12
(3d)
-2
O13
(3d)
-2
O14
(3d)
-2
O15
(3d)
-2
O16
(3d)
-2
O17
(3d)
-2
O18
(3d)
-2
Sb4
(1a)
5
Sb5
(1c)
5
Sb6
(1b)
5
Sb7
(3d)
5
Sb8
(3d)
5
O19
(3d)
-2
O20
(3d)
-2
O21
(3d)
-2
O22
(3d)
-2
O23
(3d)
-2
O24
(3d)
-2
O25
(3d)
-2
O26
(3d)
-2
O27
(3d)
-2
O28
(3d)
-2
O29
(3d)
-2
O30
(3d)
-2
O31
(3d)
-2
O32
(3d)
-2
O33
(3d)
-2
O34
(3d)
-2
O35
(3d)
-2
O36
(3d)
-2
H1
(3d)
1
0
0
0
0.01
1
0.66
0.33
0.99
0.01
1
0.33
0.66
0.90
0.01
1
0.33
0.99
0.96
0.01
1
0.67
0.00
0.94
0.01
1
0.02
0.11
0.88
0.01
1.
0.11
0.08
0.11
0.01
1.
0.74
0.29
0.87
0.01
1.
0.77
0.41
0.10
0.01
1.
0.36
0.58
0.01
0.01
1.
0.30
0.75
0.79
0.02
1.
0.30
0.08
0.83
0.02
1.
0.42
0.11
0.08
0.02
1.
0.45
0.02
0.83
0.02
1.
0.35
-.09
0.08
0.02
1.
0.24
0.87
0.83
0.02
1.
0.21
-.03
0.08
0.02
1.
0.58
0.03
0.06
0.01
1.
0.69
0.11
0.81
0.01
1.
0.79
0.09
0.06
0.02
1.
0.76
-.02
0.82
0.02
1.
0.64
0.88
0.06
0.02
1.
0.55
-.08
0.83
0.01
1.
0
0
0.49
0.01
1
0.66
0.33
0.48
0.01
1
0.33
0.66
0.41
0.01
1
0.33
0.00
0.46
0.01
1
0.66
0.99
0.44
0.01
1
0.06
0.11
0.37
0.01
1.
0.11
0.04
0.60
0.01
1.
0.78
0.37
0.60
0.01
1.
0.71
0.26
0.36
0.01
1.
0.21
0.60
0.53
0.01
1.
0.44
0.73
0.29
0.01
1.
0.26
0.05
0.34
0.01
1.
0.38
0.12
0.57
0.01
1.
0.44
0.07
0.34
0.01
1.
0.40
-.04
0.57
0.01
1.
0.28
0.89
0.34
0.01
1.
0.21
-.06
0.58
0.01
1.
0.60
0.05
0.55
0.01
1.
0.73
0.10
0.32
0.01
1.
0.77
0.04
0.56
0.01
1.
0.70
-.07
0.33
0.01
1.
0.59
0.88
0.56
0.01
1.
0.54
-.05
0.32
0.01
1.
0
48.
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