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CC=Collection Code: [AB2X4]=ANX Form: [cF56]=Pearson: [e d a]=Wyckoff Symbol: [Al2MgO4]=Structure Type:
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CC=91717
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Title
Cation partitioning in an unusual strontian potassic richterite from Siberia: Rietveld structure refinement and Mossbauer spectroscopy.
Authors
Sokolova, E.V.;Kabalov, Yu.K.;McCammon, C.;Schneider, J.;Konev, A.A.
Reference
Mineralogical Magazine (2000)
64
, 19-21
Link
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Compound
H2 Ca0.36 Fe0.16 K0.92 Mg4.84 Na1.44 O24 Si8 Sr0.28
-
[Richterite, strontian, potassic]
Sodium potassium calcium strontium magnesium iron(III) catena-octasilicate hydroxide (1.44/0.92/0.36/0.28/4.84/ 0.16/1/2)
[
AB2C5D8X24
] [
mS84
] [
j7 i2 h2 g b a
] [
]
Cell
10.0325(1), 17.9770(10), 5.2698(1), 90., 104.70(1), 90.
C12/M1 (12)
V=919.32
Remarks
R=0.032000 : X M =Richterite, strontian, potassic :
Deviation of the charge sum from zero tolerable.
Atom (site) Oxid.
x, y, z, B, Occupancy
Si1
(8j)
4
Si2
(8j)
4
Mg1
(4h)
2
Mg2
(4g)
2
Fe1
(4g)
3
Mg3
(2a)
2
Na1
(4h)
1
Ca1
(4h)
2
Sr1
(4h)
2
K1
(2b)
1
Na2
(2b)
1
O1
(8j)
-2
O2
(8j)
-2
O3
(4i)
-2
O4
(8j)
-2
O5
(8j)
-2
O6
(8j)
-2
O7
(4i)
-2
H1
(8j)
1
0.27
0.08
0.30
1.3(
1
0.28
0.17
0.80
1.2(
1
0
0.09
0.5
1.3(
1
0
0.18
0
1.0(
0.92
0
0.18
0
1.0(
0.08
0
0
0
0.8(
1
0
0.27
0.5
1.6(
0.68
0
0.27
0.5
1.6(
0.18
0
0.27
0.5
1.6(
0.14
0
0.5
0
1.7(
0.92
0
0.5
0
1.7(
0.08
0.11
0.08
0.21
0.9(
1
0.11
0.17
0.71
1.4(
1
0.10
0
0.71
0.6(
1
0.35
0.24
0.79
1.0(
1
0.33
0.12
0.09
1.1(
1
0.33
0.11
0.60
1.7(
1
0.32
0
0.30
1.3(
1.
0
0.5
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